Complex conjugation permutes the irreducible characters, because the conjugate of an irreducible representation is irreducible. This involution fixes the real-valued characters and interchanges the other characters in pairs. If there are such pairs, then conjugating permutes its rows by transpositions. ThereforeIt follows that the determinant is real when is even and purely imaginary when is odd. It never vanishes, by the preceding part. Real-valued characters include both real and quaternionic representation types; the criterion concerns values of the characters, not those two representation types separately.
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