The irreducible characters are an orthonormal basis of the space of complex class functions for the inner product
Thus the row orthogonality relation and completeness statement are
In particular the number of irreducible characters equals the number of conjugacy classes. In class-representative notation, the orthogonality relation is .
Apply completeness to the indicator of the conjugacy class of . Its expansion coefficient is , because that class has size . Evaluating at gives
The complex conjugation is part of the printed formula; dropping it would not give the general column orthogonality relation.
The matrix is square by completeness. Column orthogonality says . Taking determinants gives
In particular its determinant is nonzero.
Complex conjugation permutes the irreducible characters, because the conjugate of an irreducible representation is irreducible. This involution fixes the real-valued characters and interchanges the other characters in pairs. If there are such pairs, then conjugating permutes its rows by transpositions. Therefore
It follows that the determinant is real when is even and purely imaginary when is odd. It never vanishes, by the preceding part. Real-valued characters include both real and quaternionic representation types; the criterion concerns values of the characters, not those two representation types separately.

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