In the hydrogen–helium approximation, take helium to be helium-4, and assume essentially all neutrons remaining at the onset of efficient nuclear burning enter it. Each helium-4 nucleus contains two neutrons and two protons, hence
Here count constituent nucleons, not just free particles after burning. Neglecting the small nucleon mass difference and nuclear binding-energy correction, the helium mass is and the total baryon mass is . Thus neutron-limited helium synthesis gives
For , this yields and the hydrogen mass fraction is . The assumptions require and negligible free neutrons, deuterium and helium-3: the phrase hydrogen and helium must here mean predominantly hydrogen-1 and helium-4, not an arbitrary mixture of helium isotopes.

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