For a conductor in electrostatic equilibrium, the interior field is zero and the surface is equipotential. The tangential exterior field is zero. A thin Gaussian pillbox gives the normal jump . Thus, in vacuum and with pointing out of the conductor,These are the electrostatic boundary conditions at a conductor.
To obtain electrostatic energy in field form, integrate over the space outside the conductors, cutting it off first at a large sphere. From the Maxwell equations, and , soOn a conductor boundary, the outward normal of the integration region points into the conductor, so its flux contribution is . At the remote outer boundary the flux integral tends to zero: for a localized charge distribution, and . The divergence theorem therefore givesSince the field vanishes inside conductors,The field integral is over all space, although the charges occupy a finite volume. For a finite outer integration boundary there is additionally the term .
For the electrostatic energy of alternating-charge concentric shells, the total enclosed charge after shell isBy spherical symmetry and Gauss's law, the field is zero for , and in every subsequent gap, including outside the last shell,Although its direction alternates, its squared magnitude is the same in every gap. ConsequentlyThe coefficient of is , independent of the other radii and of the number of shells.
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