Use the Minkowski metric throughout. Taking the Hermitian conjugation of the massive Dirac equation and using the Dirac adjoint givesTaking the matrix transpose and multiplying by the charge conjugation matrix yieldsThus the charge conjugation of a Dirac field preserves the free massive Dirac equation:The unitarity of and also giveConsequentlyHere is the unitary operator acting on the relativistic quantum field, whereas acts on Dirac spinor indices.
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