Consider an element displaced upward by in hydrostatic equilibrium. Assume it quickly reaches the ambient pressure, but moves adiabatically and retains its composition. Put , , and let be the adiabatic temperature gradient. The equation of state has differentialwhere and .
At the new pressure, the parcel-to-environment density difference isWith positive pressure scale height , . The buoyancy acceleration is therefore , with stellar buoyancy frequencyA negative amplifies the displacement. For a radiative background, , so the Ledoux criterion for instability isFor uniform composition, , giving the Schwarzschild criterionEquality is marginal stability. A mean molecular weight increasing inward has and supplies a stabilizing composition term when .
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