Consider an element displaced upward by in hydrostatic equilibrium. Assume it quickly reaches the ambient pressure, but moves adiabatically and retains its composition. Put , , and let be the adiabatic temperature gradient. The equation of state has differentialwhere and .
At the new pressure, the parcel-to-environment density difference isWith positive pressure scale height , . The buoyancy acceleration is therefore , with stellar buoyancy frequencyA negative amplifies the displacement. For a radiative background, , so the Ledoux criterion for instability isFor uniform composition, , giving the Schwarzschild criterionEquality is marginal stability. A mean molecular weight increasing inward has and supplies a stabilizing composition term when .
The Eddington closure approximation with the standard surface boundary condition gives the grey atmosphere profileTogether with the specified pressure law, logarithmic differentiation givesConsequently the radiative temperature gradient isFor a monatomic perfect gas, and the adiabatic temperature gradient is . Uniform composition makes the Schwarzschild criterion applicable. The first marginal layer therefore satisfies , giving the convection onset in a logarithmic-pressure grey atmosphereThe assumed profile becomes convectively unstable for ; further inward, a self-consistent model must account for convective transport.
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