Consider an element displaced upward by in hydrostatic equilibrium. Assume it quickly reaches the ambient pressure, but moves adiabatically and retains its composition. Put , , and let be the adiabatic temperature gradient. The equation of state has differential
where and .
At the new pressure, the parcel-to-environment density difference is
With positive pressure scale height , . The buoyancy acceleration is therefore , with stellar buoyancy frequency
A negative amplifies the displacement. For a radiative background, , so the Ledoux criterion for instability is
For uniform composition, , giving the Schwarzschild criterion
Equality is marginal stability. A mean molecular weight increasing inward has and supplies a stabilizing composition term when .
The Eddington closure approximation with the standard surface boundary condition gives the grey atmosphere profile
Together with the specified pressure law, logarithmic differentiation gives
Consequently the radiative temperature gradient is
For a monatomic perfect gas, and the adiabatic temperature gradient is . Uniform composition makes the Schwarzschild criterion applicable. The first marginal layer therefore satisfies , giving the convection onset in a logarithmic-pressure grey atmosphere
The assumed profile becomes convectively unstable for ; further inward, a self-consistent model must account for convective transport.

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