For S-wave scattering, write the radial wavefunction as . In the attractive shell , the hard-core boundary condition gives
Outside the potential, choose
Continuity of the logarithmic derivative at yields
Put . The tangent addition formula gives
and solving for gives
Let
Using and in the phase-shift formula gives
By the definition of the scattering length from a partial-wave S-matrix,
Thus diverges exactly when
At each such value, an S-wave bound state lies at the continuum threshold: the exterior zero-energy radial solution becomes constant, its logarithmic derivative vanishes, and the system has a zero-energy scattering resonance. As the well deepens through the critical value, a new bound state appears and the scattering length passes through infinity and changes sign.

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