For S-wave scattering, write the radial wavefunction as . In the attractive shell , the hard-core boundary condition givesOutside the potential, chooseContinuity of the logarithmic derivative at yieldsPut . The tangent addition formula givesand solving for gives
LetUsing and in the phase-shift formula givesBy the definition of the scattering length from a partial-wave S-matrix,Thus diverges exactly whenAt each such value, an S-wave bound state lies at the continuum threshold: the exterior zero-energy radial solution becomes constant, its logarithmic derivative vanishes, and the system has a zero-energy scattering resonance. As the well deepens through the critical value, a new bound state appears and the scattering length passes through infinity and changes sign.
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