Along the pp-chain homologous sequence, is constant and therefore . Normalizing to the Sun gives the transition mass
For the CNO cycle law , the nuclear scaling becomes
The opacity law is unchanged, so . Equating them gives
and then
The effective temperature follows from the Stefan–Boltzmann law . Thus the pp branch has and , whereas the CNO branch has
On a Hertzsprung-Russell diagram, both branches rise toward larger luminosity and, conventionally, leftward toward larger temperature. They join near ; the CNO branch has the steeper -- logarithmic slope and lies to the cooler side of the extrapolated constant-radius branch at fixed luminosity.
If is the hydrogen mass fraction and the combined carbon-nitrogen-oxygen mass fraction, the reaction-pair and catalyst abundances give approximately
The CNO nuclei are catalysts, so their abundance multiplies the CNO-cycle rate rather than being consumed by the completed cycle.

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