The CNO cycle catalyses hydrogen fusion through carbon, nitrogen, and oxygen nuclei. Near , its specific energy generation is approximately proportional to and is therefore strongly concentrated near a star's centre.
If proton–proton chain heating scales as and CNO cycle heating as , their ratio at fixed hydrogen abundance scales as . Equating the rates proves the displayed crossover-temperature relation. It applies to a local power-law approximation, with unchanged coefficient normalizations apart from the catalyst abundance.
A hotter stellar core can favor a higher-barrier route despite fewer catalyst nuclei. To isolate this competition, prescribe a local hydrogen burning toy model at fixed mass density , with reference and
Choose and , rounded barrier parameters for a proton pair and proton capture on nitrogen-14. These prescribe the temperature dependence, while the following freely chosen heating normalization incorporates effective nuclear factors and deposited energy:
Here is hydrogen mass fraction, is CNO mass fraction, and is an arbitrary positive unit of stellar energy-generation rate. For and , the reference ratio is by construction. It is not a measured solar ratio. The CNO cycle bottleneck is represented by one effective rate, without evolving the existing proton-proton chain branches or catalyst network.
At , the logarithmic temperature slopes are and . The larger Coulomb barrier gives a steeper fractional response. Because these slopes change with temperature, this example retains the exponential rather than extending two fixed power laws. Writing and gives
provided the bracket is positive. With the chosen composition, . Reducing to at unchanged shifts it to . For , this catalytic route supplies no heat in this model. These are local toy crossovers: a whole star's luminosity requires integrating its stellar energy-generation rate through its stellar composition profile and stellar structure. Nuclear features, plasma screening and changes of the dominant bottleneck limit the model's extrapolation.
Figure 1.
Chosen pp and CNO heating rates and their composition-dependent crossover
. Original local toy rates at fixed density and hydrogen mass fraction 0.70. The CNO-to-pp ratio at 15 MK is chosen as 0.01 for CNO mass fraction 0.01. Exponential barrier responses give crossovers at 20.30 and 23.91 MK for the two catalyst abundances. These are model curves, not stellar measurements or a fitted solar model. Details.
A branch of the CNO cycle proceeds through proton captures on nitrogen-15 and oxygen-16, beta-plus decay of fluorine-17, and . Returning through oxygen-15 and nitrogen-15 closes the cycle. It also catalyzes the conversion of four protons into helium-4, with branch-dependent neutrino loss.
The principal CNO cycle follows , beta-plus decay to carbon-13, proton capture to nitrogen-14, proton capture to oxygen-15, beta-plus decay to nitrogen-15, and . The carbon seed is regenerated. The ordinary bottleneck is , so nitrogen-14 accumulates in cycle equilibrium.

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The CNO cycle, or carbon-nitrogen-oxygen cycle, is one of the two main fusion processes that stars use to convert hydrogen into helium, the other being the proton-proton chain reaction. The CNO cycle is particularly important in stars that are more massive than the Sun, where temperatures and pressures are sufficiently high to facilitate the reaction.