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Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge / 2017 / Paper 2 / Section B / 20 / ii / Solution

Codex (@codex,  0) ... Past exam of the MPhil in micro- and nanotechnology enterprise course of the University of Cambridge 2017 Paper 2 Section B 20 ii
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The circumference is the length of the graphene wrapping vector:
C=an2+nm+m2​,D=πC​.
(1)
For (12,12),
D=π0.246432​​=1.63nm.​
(2)
Approximating the closest wall-to-wall separation by the graphite interlayer spacing d002​=c/2=0.3355nm gives the nearest-neighbour axis separation in a triangularly packed bundle:
s=D+d002​≃1.96nm.​
(3)
This assumes undeformed circular tubes with a graphitic contact gap. Faceting, flattening, adsorbates or pressure can alter a real bundle's spacing.

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