For a closed unit-branching radioactive decay chain, the rate equations areThe first gives . Multiply the second by its integrating factor :Integrate from zero to . For ,soThe coefficients can individually be negative; the physical population is nonnegative because the production integral is nonnegative. For equal nuclear decay constants , the finite limit isA sum of two constant-coefficient copies of the same exponential function cannot represent this limit; the factor is essential.
For , differentiate the distinct-nuclear decay constant result:Equating the production and loss terms gives , henceFor positive nuclear decay constants and , this is positive regardless of their ordering. Initially , while at late times; the stationary point is the unique maximum. At that time . If the nuclear decay constants are equal, differentiating gives , also the continuous limit of the expression above.
A stable terminal product obeys . Conservation of the number of chain members gives when . Therefore, for distinct nuclear decay constants,Set for an initially absent terminal product. For equal nuclear decay constants,Both expressions have because the intermediate population initially vanishes; their leading growth is . For positive nuclear decay constants, increases monotonically to .
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