Given ϵ>0, cover E1 by open intervals of total length less than ϵ/2, and cover E2 similarly. Combining the two countable covers gives a cover of their union of total length less than ϵ. Thus E1∪E2 is a null set.
For each n≥1, choose a countable interval cover of En of total length below ϵ/2n. The union of these covers is countable and covers ⋃nEn, with total length less than ∑nϵ/2n=ϵ. As ϵ is arbitrary, acountable union of null sets is null.