A nuclear excited state has internal energy above its ground state, with levels labelled by spin and parity and, where useful, approximate isospin. In the shell model, nucleons occupy orbitals split by spin-orbit coupling; nuclear particle-hole excitation and broken pairs produce excited configurations. An orbital has parity , and an even-even paired ground state is commonly . Residual interactions mix configurations, so shell spacings are not a complete spectrum.
Collective motion gives distinct patterns. A deformed nucleus can have a rotational band with , so a simple even-even band has . Near spherical shape, a quadrupole vibration gives a one-phonon excitation; two such phonons can couple to near twice that energy in the harmonic limit. Anharmonicity and coupling to single-particle motion modify these ideal patterns.
De-excitation occurs by gamma emission, internal conversion, or particle emission if energetically open. photon multipolarity must satisfy the angular-momentum triangle rule. Electric multipoles change parity by and magnetic multipoles by ; a single photon cannot connect . Large multipolarity or a small transition matrix element can make a long-lived nuclear isomer. Gamma energies, coincidence cascades, angular correlations and lifetimes constrain level schemes; inelastic scattering and transfer reactions supply complementary spin/configuration information. One observed line alone need not identify a unique level assignment.

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