angular momentum generates rotations. Its components obey , and commutes with each component. A compatible basis has and , where . ladder operators change by one, terminate at , and give magnetic substates. Different Cartesian components generally cannot all be sharp simultaneously.
orbital angular momentum is . Its angular eigenfunctions are spherical harmonics, with integer arising from their spatial rotation properties and single-valuedness. spin is intrinsic angular momentum, not literal rotation of a finite charged sphere. It may be half-integer; spin is represented by . For several contributions, obeys the same algebra. Coupling angular momenta permits , with Clebsch-Gordan coefficients relating product and coupled bases. spin-orbit coupling can distinguish these total-angular-momentum sectors.
The Stern-Gerlach apparatus sends a collimated neutral atomic beam through an inhomogeneous magnetic field and records its deflection. A magnetic moment experiences ; field uniformity would produce precession but no analogous net separating force. A classically continuous distribution of moment orientations would broaden the beam continuously. Gerlach and Stern instead observed separated silver-beam components. Reversing or removing the field and comparing the undeflected profile controls the magnetic origin; collimation, velocity spread and finite resolution affect the spots. The original experiment demonstrated space quantization; its modern silver interpretation uses the unpaired electron spin with nearly zero orbital angular momentum, rather than a direct measurement of a free electron's trajectory.[ref]
Der experimentelle Nachweis der Richtungsquantelung im Magnetfeld by Walther Gerlach and Otto Stern. Experimental setup, recorded silver deposits and field-on/off comparison
For two spin- particles, the triplet state sector has and symmetric spin statesThe spin singlet state has and antisymmetric spin stateTheir total values are and zero, while has values and . The singlet is rotationally invariant and gives anticorrelated spin measurements along a common axis. For identical fermions the complete state is antisymmetric: a symmetric spatial state pairs with a singlet spin state, whereas an antisymmetric spatial state pairs with triplet spin. Orbital, spin and coupled angular momenta share an algebra, but their physical origins and allowed representations differ.
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