A characteristic function is useful for proving convergence in distribution, including for laws without a finite moment-generating function: the continuity theorem says that pointwise convergence of characteristic functions to a characteristic function continuous at zero implies convergence in distribution to its law. For example, the Cauchy distribution has a characteristic function although its moment-generating function is not finite on any neighbourhood of zero.
A moment-generating function is especially useful for exponential tail bounds: for where it is finite, Markov's inequality gives
Optimizing over yields a Chernoff bound. The positive real exponential in this argument permits the inequality; a unit-modulus complex exponential does not give the corresponding tail bound.

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