At nonzero band hybridization, the crossing becomes an avoided crossing. The separation at is . If , appreciable mixing occurs only where ; away from that region each branch retains nearly its original orbital character. For , the avoided crossing is broad and both branches are substantially reshaped, as shown in the figure.
Use for the lower branch and for the upper one. For ,The lower branch increases towards from below. Thus an indirect gap exists in the exactly flat-band model. In the unbounded-parabola limit its lower bound isA finite Brillouin zone gives a finite maximum of below and hence a slightly larger indirect gap. This hybridization gap differs from the local direct gap .
The material can therefore be a band insulator when the lower band is full and the upper band empty. With two spin-degenerate orbitals per unit cell, the required filling isWith spin degeneracy removed, replace two by one for each independent spin sector. Other fillings are metallic in this noninteracting model.
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