First conjugate the Dirac equation: . A matrix taking into another solution of the same Dirac equation must obeyBecause anticommutes with the real and commutes with the purely imaginary , a unitary choice isAny constant overall phase is equally valid. To verify invariance of the action, rather than only of its equation, keep the fermion exchange signs. Define the charge-conjugation matrix . It obeysFor a classical Grassmann field, interchanging two components contributes a minus sign; equivalently use normal ordering for quantum fermionic operators. ThusandThe last term integrates to a boundary term, vanishing with the usual decay or compatible boundary conditions. Both the kinetic term and the Dirac mass term therefore leave invariant under charge conjugation. Treating the components as commuting numbers would give the wrong mass-bilinear sign; the fermion statistics is essential.
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