The normalized Hartree product state and its equivalent second quantization form areThe product is already symmetric under exchanging bosons; no additional belongs in the coordinate wavefunction. The factor in the second quantization expression instead normalizes repeated creation operators acting on the vacuum state. This is a fixed-number two-mode condensate, with every boson in the same normalized orbital.
Set and . Its binomial distribution of occupations givesThe expectation value of the Hamiltonian operator is thereforeKeeping rather than replacing it by retains the exact pair count of the trial quantum state. Equivalently, with , its interaction contribution is and its one-particle contribution is .
Choose the nonredundant parameter range , with modulo . For , minimizing over the relative phase gives . Putting , the remaining nonconstant energy is , which decreases with for the repulsive coupling . HenceThe optimal orbital is the symmetric . Both the quantum tunnelling term and the repulsive interaction favor this balanced occupation within the Hartree product state family. This result uses a variational method: for strong repulsion relative to quantum tunnelling, the true many-body ground state can have smaller occupation fluctuations than this fixed-number two-mode condensate.
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