One mole of original atoms contains (1−ζ) moles of neutral atoms, ζ moles of protons and ζ moles of electrons. All are monatomic translational species, so their combined thermal energy is 23RT(1+ζ). Taking the neutral ground state as zero internal energy, ionization stores ζNAEI. ThusRadiation, excited states and nonideal interactions have been excluded consistently with the elementary Saha ionization equation.
U=23RT(1+ζ)+ζNAEI=23RT(1+ζ)+ζkBTEIRT.
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