Write x=ΔE/(kBT) and r=N↑/N↓=e−x. Since N=N↑+N↓, eliminate the individual populations:The Taylor expansion e−x=1−x+O(x2) gives the same result, and the odd expansion of the hyperbolic tangent yieldsEquivalently, N↑≃(N/2)(1−x/2) and N↓≃(N/2)(1+x/2). Their sum is still N. The negative sign follows directly from the stated higher-energy up-state population, and does not mean a negative magnitude of the equilibrium magnetization.
NN↑−N↓=r+1r−1=e−x+1e−x−1=−tanh2x.
NN↑−N↓=−2x+O(x3)≃−2kBTℏγB.
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