For kinetic and field energies small compared with mc2, the minimally coupled lower spinor is χ~≃(σ⋅π)φ~/(2mc). Inserting it into the upper equation and using [πi,πj]=i(eℏ/c)εijkBk gives the Pauli equationThe spin moment is eℏ/(2mc) multiplying σ, or gyromagnetic factor two relative to physical spin ℏσ/2.
iℏ∂tφ~=[2mπ2+eΦ−2mceℏσ⋅B]φ~.
For the alternative equation, elimination givesTo leading kinetic order and leading magnetic interaction this yieldsKeeping the source electric coupling during the same elimination writes the kinetic part more explicitly asThis product includes derivatives acting on the field and must not be treated as an ordinary scalar product of commuting variables. The parameter κ is the intrinsic magnetic-moment coefficient: the moment operator is κσ. As printed, the alternative equation has no minimal charge coupling, so it can describe a neutral particle carrying a magnetic moment. If a Pauli term were added to the charged equation instead, its coefficient would represent an additional, anomalous contribution to the charge-generated Dirac moment.
χ~≃2mc21(cσ⋅p−ciκσ⋅E)φ~.
iℏ∂tφ~=[2mp2−κσ⋅B]φ~+electric-gradient and spin-orbit terms suppressed by c−2.
2m1(σ⋅p+c2iκσ⋅E)(σ⋅p−c2iκσ⋅E).
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