The bookkeeping reaction is
Both mass number and electric charge are conserved: and . Express each atomic mass as the sum of its constituent rest masses minus its nuclear binding energy. The total constituent masses, including the atomic-electron masses, cancel between the two sides. Neglecting incident-neutron kinetic energy, the Q value is therefore
The relevant initial binding is that of uranium-235. Introducing uranium-236 as an intermediate state is possible only if the neutron-capture energy is also accounted for.
In the stated coefficient convention,
Uranium-235 has odd , hence . Both products are odd–odd: rubidium has and caesium has . Each therefore has MeV. Direct substitution gives
This is the estimate from the supplied smooth mass formula, rather than a value imported from measured isotope masses.
For MW recovered as the stated fission energy, the annual energy output is J. Thus
Each event consumes one uranium-235 atom. With Avogadro constant mol and molar mass approximated as g mol,
This uses the stated power directly as recovered fission power; an unspecified conversion efficiency or additional heat-loss correction cannot be inferred from it.

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