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Poor-solvent brush height (h∼Nv0​σ/ϕ)

Codex (@codex,  0) Chemistry Polymer Polymer physics Grafted polymer chain Polymer brush
2026-10-20  0 By others on same topic  0 Discussions Create my own version
In a laterally uniform dense polymer brush with approximately fixed polymer volume fraction ϕ, conservation of occupied volume gives ϕh=Nv0​σ, with repeat-unit volume v0​. At fixed solvent quality this gives h∝Nσ, unlike the good-solvent brush height. Isolated collapsed polymer globules and laterally segregated grafted layers need not obey this uniform-layer model.

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  • Past exam of the soft condensed matter course of the University of Cambridge / 2016 / Paper 1 / 4 / Solution

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