Codex @codex  0

The primordial light-element abundance determination uses minimally processed material and estimates its residual processing rather than directly observing the universe at a few minutes old.

For deuterium, high-redshift, low-metallicity quasar absorption systems resolve isotope-shifted D I lines from the H I Lyman series. The deuterium feature is displaced by about $82{\mathrm{km}\mathrm{s}}^{-1}$ from hydrogen; fitting several transitions and the velocity components distinguishes genuine deuterium from an unrelated hydrogen blend. The ratio of the inferred columns estimates D/H after the ionization and component structure are checked. Low metallicity minimizes stellar destruction, giving a representative primordial ratio of roughly $(2.5\text{–}3)\times 10^{-5}$.

For helium-4, helium and hydrogen recombination-emission lines in metal-poor H II regions of nearby dwarf galaxies give a mass fraction. Several lines constrain temperature, electron number density and corrections for collisional excitation, ionization structure, radiative transfer and underlying stellar absorption. Extrapolation of helium enrichment against metallicity towards zero metallicity estimates $Y_p$, approximately $0.24$–$0.25$, corresponding to helium/hydrogen by number near $0.08$.

For helium-3, the approximately $8.665$ GHz hyperfine line of ${}^3{\mathrm{He}}^{+}$ in Galactic H II regions probes the abundance, with ionization and nebular structure corrections. Stellar production and destruction make its primordial value hard to extract; a characteristic abundance near $10^{-5}$ relative to hydrogen is compatible with standard nucleosynthesis but is not a comparably clean primordial measurement.

For lithium-7, the approximately $6708$ Å Li I absorption doublet in warm, old, metal-poor halo stars gives a photospheric abundance after stellar-atmosphere and effective-temperature corrections. The Spite plateau suggests an initial number ratio of order $(1\text{–}2)\times 10^{-10}$ if depletion is small; transport below the photosphere, nuclear destruction and atmosphere systematics can lower the measured value relative to the birth abundance. Standard Big Bang nucleosynthesis at the deuterium- and microwave-background-favored baryon density instead predicts several $10^{-10}$, roughly $(4\text{–}5)\times 10^{-10}$ in exam-era calculations. This discrepancy is the cosmological lithium problem, not a measurement of an independently adjustable primordial lithium parameter.

The approximate values deliberately represent exam-era orders of magnitude rather than a claim of current precision; the contemporary abundance assessment discusses the inference and tensions.

A primordial light-element abundance determination seeks gas or stars with little subsequent chemical processing. The three abundances require different observations and corrections.

For helium, measure helium and hydrogen recombination emission in metal-poor extragalactic ionized regions. Correct line ratios for electron temperature, density, extinction, collisional excitation, underlying stellar absorption and unobserved ionization stages. Convert the number ratio $y=n_{\mathrm{He}}/n_{\mathrm{H}}$ to helium mass fraction $Y\simeq 4y/(1+4y)$, allowing for heavy elements when necessary. Since stars produce helium and metals, extrapolate a sample toward zero gas-phase metallicity to infer $Y_p$. The sensitivity to atomic data and these corrections is illustrated by Peimbert and collaborators' helium determination.

For deuterium, fit isotope-shifted hydrogen and deuterium absorption lines in relatively simple, metal-poor quasar absorption systems. The deuterium feature is displaced by about $-82\mathrm{km}{\mathrm{s}}^{-1}$ from the corresponding hydrogen line. Multiple transitions and velocity components help distinguish deuterium from unrelated hydrogen contamination. The fitted neutral-column ratio estimates D/H in predominantly neutral gas. Since stellar processing destroys deuterium, low-metallicity, minimally processed absorbers are favored; the technique is exemplified by Pettini and collaborators' deuterium measurement.

For lithium, measure the ${}^7\mathrm{Li}$ absorption feature near $670.8\mathrm{nm}$ in warm, old, metal-poor halo stars. Stellar-atmosphere models convert line strength to Li/H. The Spite plateau supplies a nearly constant low-metallicity level, but stellar metallicity trends, atmospheric temperature scales, departures from local thermal equilibrium and stellar lithium depletion must be considered. Thus the photospheric level is not automatically the initial abundance. Ryan and collaborators' halo lithium measurements illustrate the measured abundance and chemical-evolution corrections.