A primordial light-element abundance determination seeks gas or stars with little subsequent chemical processing. The three abundances require different observations and corrections.
For helium, measure helium and hydrogen recombination emission in metal-poor extragalactic ionized regions. Correct line ratios for electron temperature, density, extinction, collisional excitation, underlying stellar absorption and unobserved ionization stages. Convert the number ratio to helium mass fraction , allowing for heavy elements when necessary. Since stars produce helium and metals, extrapolate a sample toward zero gas-phase metallicity to infer . The sensitivity to atomic data and these corrections is illustrated by Peimbert and collaborators' helium determination.
For deuterium, fit isotope-shifted hydrogen and deuterium absorption lines in relatively simple, metal-poor quasar absorption systems. The deuterium feature is displaced by about from the corresponding hydrogen line. Multiple transitions and velocity components help distinguish deuterium from unrelated hydrogen contamination. The fitted neutral-column ratio estimates D/H in predominantly neutral gas. Since stellar processing destroys deuterium, low-metallicity, minimally processed absorbers are favored; the technique is exemplified by Pettini and collaborators' deuterium measurement.
For lithium, measure the absorption feature near in warm, old, metal-poor halo stars. Stellar-atmosphere models convert line strength to Li/H. The Spite plateau supplies a nearly constant low-metallicity level, but stellar metallicity trends, atmospheric temperature scales, departures from local thermal equilibrium and stellar lithium depletion must be considered. Thus the photospheric level is not automatically the initial abundance. Ryan and collaborators' halo lithium measurements illustrate the measured abundance and chemical-evolution corrections.
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