For a symmetric two-dimensional thin drop with uniform evaporative loss , a freely receding contact line and fixed leading outer contact angle , quasistatic capillary balance makes the height quadratic. Its volume per transverse length is . Since and the contact-line flux vanishes, volume loss is . On slow time , this gives the stated constant recession speed.
Substitute that speed into and integrate flux from the centre, obtaining . Division by height gives the displayed inward velocity. With a pinned width instead, the same uniform-loss model gives and outward velocity . Thus the contact-line assumption alone reverses solute transport. A pinned perimeter can produce a coffee-ring effect; the receding fixed-angle outer model predicts central transport instead. A strictly no-slip sharp moving contact line is singular, so the finite outer angle is a leading quasistatic approximation requiring microscopic regularization at finite speed.
Articles by others on the same topic
There are currently no matching articles.