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Associate to each prime $p\equiv 3(\mathrm{mod}4)$ the class of $(-1,p{)}_{\mathbb{Q}}$. These classes have order two, since quaternion conjugation identifies the algebra with its opposite. The product rule $[(-1,a)][(-1,b)]=[(-1,ab)]$ follows by factoring their tensor product into the commuting subalgebras generated by $i_1,j_1{j}_2$ and by $i_1{i}_2,j_2$; the second is the split algebra $(1,b)$. Every nonempty finite product of distinct such primes has an odd valuation at one of them. The quaternion norm obstruction at primes congruent to three modulo four therefore makes its class nonzero, proving independence. Euclid's construction $4p_1\cdots p_m-1$ proves there are infinitely many such primes.

We first prove the simple Artinian case of the Artin–Wedderburn theorem. This part does not need finite dimension over $k$. Choose a minimal nonzero left ideal $L$, using the descending chain condition. Simplicity gives $LA=A$. Also $L^2\ne 0$: otherwise $LAL=(LA)L=L$ would be zero, since each $la{l}^{\prime }$ lies in $L^2$. Choose $x\in L$ for which right multiplication $r_x:L\to L$ is nonzero. By simplicity of $L$, it is an automorphism. Choose $e\in L$ with $ex=x$. Then $(e^2-e)x=0$, and injectivity of $r_x$ gives $e^2=e$. Thus $L=Ae$.

Right multiplication by $e$ splits the left regular module as $A=Ae\oplus A(1-e)$. Repeat within the remaining left ideal: if it contains a minimal left ideal $Af$ generated by an idempotent, the map $v\mapsto vf$ splits off $Af$. Each nonzero remaining complement is a strictly smaller left ideal, so the Artinian condition terminates the process. Therefore the regular module is a finite direct sum of minimal left ideals.

All these simple summands are isomorphic. For primitive idempotents $e,f$, simplicity gives $AeA=A$, so $fAe\ne 0$; otherwise $fAeA=fA$ would be zero. A nonzero element of $fAe$ defines a nonzero homomorphism $Af\to Ae$, which is an isomorphism between simple modules. Thus $A\cong L^{\oplus n}$ as a left module. Put $\Delta ={\mathrm{End}}_A(L)$, a division algebra by the Schur lemma. Right multiplication givesTaking opposites, with matrix transposition reversing products, provesThe construction is $k$-linear and embeds $k$ into the center of $D$.

A central simple algebra is a finite-dimensional simple $k$-algebra whose center is exactly $k$. The Brauer group consists of such algebras modulo matrix stabilization: $A,B$ represent the same class if $M_r(A)\cong M_s(B)$ for some positive integers $r,s$. Its operation and inverse areThe tensor product is central simple, and $A\otimes A^{\mathrm{op}}\cong {\mathrm{End}}_k(A)$ by $(a\otimes b)(x)=axb$, explaining the inverse. Both facts can be checked after a splitting field of a central simple algebra extension, where they are matrix-algebra identities, and descended by faithful scalar extension. Every class has a unique central division-algebra representative, by the regular-module description above.

To prove infinitude over $\mathbb{Q}$ explicitly, put $E=\mathbb{Q}(i)$ and, for $a\ne 0$, letThis is a quaternion algebra. It is central simple: the center is $\mathbb{Q}$, and after adjoining $i$ its generators have the faithful matrix modelThese generate $M_2(E)$; consequently a nonzero proper two-sided ideal over $\mathbb{Q}$ is impossible. The quaternion conjugation givesA nonzero element has an inverse exactly when this norm is nonzero. Thus $A_a$ is a division algebra when $a$ is not an $E/\mathbb{Q}$ norm; if $a$ is a norm it has a nonzero zero divisor and is $M_2(\mathbb{Q})$ by the classification just proved.

For a prime $p\equiv 3(\mathrm{mod}4)$, every nonzero rational sum $x^2+y^2$ has even $p$-adic valuation. Divide out the minimum valuation of $x,y$; cancellation modulo $p$ is impossible because $-1$ is not a square modulo $p$. Therefore $p$ is not an $E/\mathbb{Q}$ norm, and $A_p$ is a nontrivial division-algebra Brauer class. This is the quaternion norm obstruction at primes congruent to three modulo four.

We also prove the product rule needed to distinguish classes. In $A_a\otimes A_b$, write the generators as $i_1,j_1,i_2,j_2$. The commuting subalgebras generated respectively byare $A_{ab}$ and the split quaternion algebra $(1,b{)}_{\mathbb{Q}}\cong M_2(\mathbb{Q})$. The latter has the matrix model $\mathrm{diag}(1,-1)$ and $\left(\begin{array}{cc}0& b\\ 1& 0\end{array}\right)$. Together the two subalgebras generate the whole tensor product, since they recover $i_2$ and $j_1$. Dimensions are sixteen on both sides, givingQuaternion conjugation identifies $A_a$ with its opposite, so these classes have order at most two. For distinct primes $p,q\equiv 3(\mathrm{mod}4)$, the parameter $pq$ has odd valuation at $p$, so $A_{pq}$ is a division algebra. Thus $[A_p]\ne [A_q]$. There are infinitely many such primes: if their list were $p_1,\dots ,p_m$, the integer $4p_1\cdots p_m-1$ would have a prime factor congruent to three modulo four outside that list. We concludeIndeed the same valuation argument for any nonempty finite product gives independent quaternion classes over rational numbers.

For $\mathbb{R}$, we prove the required division-algebra classification. Let $D$ be finite-dimensional and central over $\mathbb{R}$. If $D\ne \mathbb{R}$, choose a nonreal element; its irreducible real minimal polynomial is quadratic, so translating and rescaling it gives $i\in D$ with $i^2=-1$. The centralizer $D_{+}$ of $i$ is a finite-dimensional division algebra over $\mathbb{C}=\mathbb{R}(i)$, with that field central. Every element has a split minimal polynomial over $\mathbb{C}$, hence belongs to $\mathbb{C}$, so $D_{+}=\mathbb{C}$.

Conjugation by $i$ is an involution, giving $D=D_{+}\oplus D_{-}$, where $D_{-}=\{x:ix=-xi\}$. If $D_{-}=0$, then $D=\mathbb{C}$, contrary to its center being $\mathbb{R}$. Choose $j\ne 0$ in $D_{-}$. For any $x\in D_{-}$, $x{j}^{-1}$ commutes with $i$, so $D_{-}=\mathbb{C}j$. Also $j^2\in \mathbb{C}$ and commutes with $j$, forcing $j^2\in \mathbb{R}$. It cannot be positive, since $(j-\sqrt{j^2})(j+\sqrt{j^2})=0$, or zero, since $D$ is a division algebra. Rescale to $j^2=-1$. ConsequentlyConversely the positive definite quaternion norm makes $\mathbb{H}$ a division algebra. The two possible central division representatives are therefore $\mathbb{R}$ and $\mathbb{H}$. They are not equivalent, and conjugation identifies $\mathbb{H}$ with its opposite, soThis uses the finite-dimensional real division-algebra classification directly, not as an unexplained theorem citation.

Finally let $k_s$ be a separable closure and $\Gamma =\mathrm{Gal}(k_s/k)$. The cohomological description isHere $k_s^{\times }$ has the discrete topology and its natural Galois action. For a finite Galois splitting field $L$, identify $A{\otimes }_{k}L$ with a matrix algebra. Its descent action is implemented by matrices $u_{\sigma }$, unique up to scalars, soThe inverse convention here agrees with the crossed-product convention below. The semilinear operators $u_{\sigma }\sigma$ commute with the descended algebra $A$; their crossed product has class $[A{]}^{-1}$ by the commuting-factor decomposition of the full endomorphism algebra. Inverting its scalar cocycle therefore gives the class $[A]$. Associativity gives the two-cocycle identity, and changing the representatives changes $c$ by a coboundary. Conversely a two-cocycle defines the crossed-product algebra of a Galois extension, with $u_{\sigma }a=\sigma (a)u_{\sigma }$ and $u_{\sigma }{u}_{\tau }=c(\sigma ,\tau )u_{\sigma \tau }$. It is central simple and split by $L$. Galois descent identifies coboundaries with split matrix-algebra classes and gives $H^2(\mathrm{Gal}(L/k),L^{\times })\cong \ker (\mathrm{Br}(k)\to \mathrm{Br}(L))$. Every central simple algebra has a finite separable, hence finite Galois, splitting field, yielding the displayed limit.