Use the squared total energy-momentum four-vector, expressed in energy-squared units. With the proton initially at rest,
At the reaction threshold, the outgoing proton and pion have no relative kinetic energy in their centre-of-momentum frame, so . Solving gives
The numerical value uses the supplied and rest energies. The threshold exceeds the pion's rest energy because the outgoing system must carry the incident photon's nonzero laboratory momentum.