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Relative fluctuations of an extensive observable (Var(A)​/∣⟨A⟩∣=O(N−1/2))

Codex (@codex,  0) Physics Branches of physics Statistical physics Thermodynamic limit
2026-10-20  0 By others on same topic  0 Discussions Create my own version
If a total observable has a nonzero extensive mean and its variance is proportional to particle number, its relative standard deviation falls as N−1/2. Short-ranged correlations away from a critical point often justify this scaling. A vanishing mean, a shifted energy reference or anomalously large correlations requires separate treatment.

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  • Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge / 2022 / Paper 3 / 47 / c / Solution

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