For a fixed sphere and fixed refractive index, both the Rayleigh scattering cross-section and scattering efficiency are proportional to . Halving wavelength multiplies either by , as long as the shorter wavelength still satisfies . If optical dispersion changes , the material factor changes too; the pure fourth-power comparison then needs correction.
For equal incident light intensities at blue wavelength and red wavelength , the same toy sphere gives
Blue light therefore produces about times the scattered power. This compares the particle's response at two wavelengths; it does not assert that an actual sky has this ratio of observed blue and red light intensities.
Figure 1.
Rayleigh scattering wavelength dependence for a fixed small sphere, normalized at
. The curve is over to . Blue and red comparison points are marked at and . Fixed radius and nondispersive refractive index are assumed, with throughout. This is a particle response curve, not a simulated sky optical spectrum. Details.
Scattering efficiency 2026-10-14
For a sphere of radius , the scattering efficiency is its effective scattering area divided by the projected geometric cross-section . It is a dimensionless quantity. For Rayleigh scattering by a small sphere with relative refractive index and incident wavenumber ,
At fixed wavelength and fixed refractive index, the Rayleigh scattering cross-section scales as , whereas the scattering efficiency scales as . Doubling radius multiplies the former by and the latter by . An efficiency here is an effective scattering area relative to a reference area, rather than a fraction of all light in an arbitrary beam.
For a worked toy example, take , , and . Then and . Substitution gives Rayleigh scattering cross-section and scattering efficiency . At incident light intensity , the scattered power is approximately . These are leading small-particle estimates, not a measured air-molecule cross-section.