Particle pushing by a freezing front 2026-10-14
A planar freezing front can push a spherical particle steadily when repulsive sphere-plane dispersion force balances lubrication resistance. The thin parabolic gap gives hydraulic drag , and balancing it against gives the displayed speed. This balance assumes a nonretarded interaction, small gap and negligible inertial and other particle forces.
Past exam of the mathematics course of the University of Cambridge 2003 iii Paper 77 3 Solution Created 2026-10-03 Updated 2026-10-14
Take an attractive nonretarded molecular potential , with molecular number densities . Its force magnitude is . For one molecule at height above a half-space, integration over cylindrical radius and depth givesIts downward force is . A sphere's horizontal cross-section a distance above its bottom has area , so its total attractive force isFor the near-bottom region dominates. Replacing its area by and extending the upper limit givesThis derives the sphere-plane dispersion force from the pairwise Van der Waals force. Hereafter denotes the magnitude of the effective repulsive interaction across water, rather than the signed attractive Hamaker constant. Its planar pressure magnitude is .
For a nearly planar freezing front, the spherical gap is . In the particle frame the incoming normal motion has speed . Axisymmetric mass conservation gives the outward gap flux per circumference . The lubrication flux law therefore givesIntegrating its axial force givesSteady particle pushing by a freezing front requires , and henceThe viscous drag is not the isolated-sphere Stokes drag: its divergence as the gap closes is essential.
For the deformed interface let and measure from the sphere's downward pole, as in the original geometry. The height below the remote melting isotherm is . Under the imposed temperature gradient, the undercooling is . With capillary depression neglected, the local phase-equilibrium pressure isHere is the absolute melting temperature; a constant reference ice density is used in the thermomolecular relation. ThusThe numerical value of will cancel from the speed relation.
In the thin spherical film, incompressibility and the incoming normal velocity giveSymmetry supplies zero pole flux. The tangential Couette contribution is smaller by and is negligible at this order. Applying the pressure-driven flux law along arclength giveswhere pressure is matched to the outer liquid at .
A cap area element is and its vertical normal component is . Put . The upward molecular and downward hydraulic forces are thereforeBalancing these forces establishes premelted-film particle pushing:The factorizations are and . They confirm positivity on the physical cap range and provide a numerically better-conditioned shallow-cap expression. Since , the shallow-cap limit within is ; it is not a limit in which the film can be identified with the flat-front gap .
The local film formula diverges right at the rim . Accordingly the thin-film calculation is an outer approximation away from a small matching fringe, not a claim of a uniformly thin film at its contact with bulk water. Both integrated stress densities vanish at that rim; in the thin-film limit the fringe contributes only a higher-order correction. Surface-tension curvature, altered thermal gradients or appreciable density-change fluxes would require a different balance.