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For a spherical square well of radius $a$, depth $V_0$ and reduced mass $\mu$, the regular zero-orbital angular momentum solution has reduced radial wavefunction $U=A\sin kr$ inside and $U=B{e}^{-qr}$ outside. Wavefunction matching at a finite potential step gives $k\cot (ka)=-q$, where $k^2=2\mu (V_0+E)/{\hslash }^2$ and $q^2=-2\mu E/{\hslash }^2$. The $n$th radial branch first reaches $E=0$ at $ka=(n+1/2)\pi$, for $n=0,1,\dots$. A normalizable negative-energy state on that branch requires $V_0>V_{s,n}$. Thus exactly one such state exists for $V_{s,0}<V_0\le V_{s,1}$; the new zero-energy $s$-wave solution at the upper equality is not normalizable.

For the first $\ell =1$ branch, the zero-energy exterior solution has $U\propto r^{-1}$. The regular interior solution is $U\propto r{j}_1(kr)$, where $j_1$ is a Spherical Bessel function. Matching logarithmic derivatives gives $1+z{j}_1^{\prime }(z)/j_1(z)=-1$, or $j_0(z)=0$, with $z=a\sqrt{2\mu V_0}/\hslash$. Its first threshold is $z=\pi$, so $V_{p,0}={\pi }^2{\hslash }^2/(2\mu a^2)$. Higher values of orbital angular momentum increase the positive centrifugal potential, so none can bind below this first $p$-wave threshold. Spin-dependent nuclear forces are absent from this central-well model.

The exact spherical square well matching equation is $k^{\prime }\cot (k^{\prime }a)=k\cot (ka+{\delta }_0)$. For $E\ll V_0$ near a threshold peak, neglecting $ka$ relative to the chosen scattering phase shift and replacing $k^{\prime }$ by $\kappa$ gives ${\sigma }_{\mathrm{res}}\simeq (4\pi /k^2)E/[E+V_0{\cot }^2(\kappa a)]$. Its maxima approach the S-wave bound-state threshold in a spherical square well. Its formal zeros at $\kappa a=n\pi$ are outside that approximation's validity: the exact zero-energy scattering length is then $a$, whereas genuine leading-order zeros satisfy $\tan (\kappa a)=\kappa a$.

The asymptotic scattering wavefunction is $\Psi \sim e^{ikz}+f(\theta )e^{ikr}/r$. For a real central potential, the scattering phase shift ${\delta }_l$ multiplies the outgoing component of each partial wave relative to the incoming one by $e^{2i{\delta }_l}$. Matching the incident-wave normalization givesSubtract the given incident plane wave expansion. Since $e^{2i{\delta }_l}-1=2i{e}^{i{\delta }_l}\sin {\delta }_l$, the scattering amplitude isOrthogonality ${\int }_{-1}^1{P}_l{P}_{j}dx=2{\delta }_{lj}/(2l+1)$ eliminates cross terms in $\sigma =\int |f{|}^{2}d\Omega$, giving $\boxed{\sigma =(4\pi /k^2)\sum _l(2l+1){\sin }^2{\delta }_l}$.

For the spherical square well, the regular reduced radial $l=0$ wave is $A\sin (\kappa r)$ inside and $B\sin (kr+{\delta }_0)$ outside, with ${\kappa }^2=k^2+{\gamma }^2$. Continuity of the wave and its derivative gives the logarithmic-derivative matching relation $\kappa \cot (\kappa a)=k\cot (ka+{\delta }_0)$, orAt zeros of the denominators the original matching relation supplies the limiting interpretation.

Under the stated deep-well approximation, put $x=ka$ and $B_0=\tan (\gamma a)/(\gamma a)$. The condition ${\delta }_0\in \pi \mathbb{Z}$ is $\tan x/x=B_0$. If $B_0<0$, its first positive solution lies in $(\pi /2,\pi )$; if $B_0=0$, it is $\pi$. For $0<B_0\le 1$, a solution lies in $(\pi ,3\pi /2)$ because there $\tan x/x$ rises continuously from zero to infinity. If $B_0>1$, the first positive solution lies in $(0,\pi /2)$, where $\tan x/x$ rises from one to infinity. The limiting pole case gives $x=\pi /2$ by the cotangent relation. Thus $\boxed{0<k_0<3\pi /(2a)}$, without calculating the integer phase index. The use of $\kappa \simeq \gamma$ presumes the located wave numbers remain small compared with $\gamma$.

Use the relative coordinate and reduced massTake $V=-V_0$ inside, $V=0$ outside, and $E=-B$. For $V_0>B>0$, define inverse lengthsThe radial equation becomes $u^{\prime \prime }+k^{2}u=0$ inside and $u^{\prime \prime }-{\kappa }^{2}u=0$ outside. Finiteness of the full wavefunction at the origin imposes $u(0)=0$; normalizability excludes the growing exterior exponential. HenceContinuity of $u$ was built in. Continuity of its derivative at the finite step givesFor the nodeless ground state, $\pi /2<kb<\pi$ selects the first branch. Higher roots would correspond to different wells with more bound states. Normalization is

For the requested weak-binding estimate, $B/V_0\to 0$ makes $\kappa /k\to 0$. On the first branch $kb\to \pi /2$, and $k^2\simeq 2\mu c^2{V}_0/(\hslash c{)}^2$. The leading threshold estimate isThis is the zero-binding threshold of a spherical square well, so nonzero positive binding needs a depth above it. Corrections start at order $\sqrt{B}$, not just at order $B$: setting $kb=\pi /2+ϵ$ gives $ϵ\simeq \kappa b/(\pi /2)$ and

The actual numbers permit an accuracy check: $\kappa =0.231608{\mathrm{fm}}^{-1}$ and $\kappa b=0.486377$ are not extremely small. Retaining the exterior decay, solveThis gives $x=kb=1.830503$, and the full square-well result isNeglecting $B$ only in the interior kinetic relation while retaining the measured exterior decay instead estimates $V_0\simeq 31.50\mathrm{MeV}$. These approximations should be identified: 23.2 MeV is the leading $B\to 0$ threshold, whereas matching the supplied nonzero binding requires a boundary phase shift and a deeper well.

A spherical square well is a central potential equal to a negative constant inside a sphere and zero outside it. For an S-wave scattering state with exterior wave number $k$, the interior wave number obeys ${\kappa }^2=k^2+2m{V}_0/{\hslash }^2$. Continuity of the reduced radial wave and its derivative gives $\kappa \cot (\kappa a)=k\cot (ka+{\delta }_0)$, relating the depth to the scattering phase shift.

For an attractive spherical square well, let $\kappa =\sqrt{2m{V}_0}/\hslash$. At zero energy, the outer reduced radial wave is proportional to $r-a_s$ and the regular inner wave to $\sin (\kappa r)$. Matching their logarithmic derivatives gives $a_s=a-\tan (\kappa a)/\kappa$. Away from a threshold and at sufficiently low energy, the total S-wave scattering scattering cross-section tends to $4\pi a_s^2$. The length can be negative, zero or divergent.