A spin factor and disconnected contour branches count different independent contributions. For the transition energy , one branch contributes , with . The full two-branch saddle doubles this. A formula for one branch with spin degeneracy two can therefore equal a full-contour formula with spin degeneracy one, but those are distinct counting conventions. An extra valley or inequivalent saddle requires its own multiplicity.

Articles by others on the same topic (0)

There are currently no matching articles.