Hot Electrons in galaxy clusters scatter photons of the cosmic microwave background, producing a characteristic spectral distortion. The thermal contribution measures a line-of-sight integral of Electron pressure, whereas X-ray emission depends approximately on the integral of Electron density squared times a temperature-dependent emissivity. Combining the two with a geometrical model can constrain a cluster's physical size and hence its angular diameter distance. Temperature structure and departures from the assumed geometry introduce systematic uncertainty.
For a uniform spherical cluster of depth , thermal bremsstrahlung gives received bolometric flux , while the Rayleigh-Jeans law limit of the thermal Sunyaev-Zeldovich effect gives . Eliminating and using yields the displayed angular diameter distance. A model for the density profile fixes its numerical coefficient. Clumping, nonsphericity and temperature structure can bias this distance because the two observables weight the gas differently.
Bulk motion of a scattering electron cloud relative to the cosmic microwave background gives a first-order Doppler temperature shift. With positive directed away from the observer, the displayed sign applies, and is the Thomson scattering optical depth. In the nonrelativistic, single-scattering limit it has the spectrum of a small blackbody temperature change, unlike the thermal Sunyaev-Zeldovich effect.
For a Planck photon distribution, the hot-electron Kompaneets equation gives , where . The equivalent thermodynamic temperature perturbation has the displayed form, while the Rayleigh-Jeans law gives . The distortion changes sign at . This first-order expression assumes a small Compton y parameter and nonrelativistic thermal Electrons.

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