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The BCS gap equation makes the superconducting gap function self-consistent with the BCS anomalous average that creates it. For a translation-invariant spin-singlet mean-field approximation, define ${\xi }_k={ϵ}_k-\mu$ and $E_k=\sqrt{{\xi }_k^2+|{\Delta }_k{|}^2}$. ThenThe interaction $V_{k{k}^{\prime }}$ and its normalization/cutoff are part of the model. A nonzero solution describes pairing; ${\Delta }_k=0$ is always a solution, so finding any solution alone does not establish which state minimizes the free energy.

For constant attraction $-V$ in a symmetric shell $|\xi |<\Lambda$ with constant single-spin density of states ${\nu }_s$, the zero-temperature equation reduces toAt weak coupling, this gives $\Delta \simeq 2\Lambda e^{-1/({\nu }_{s}V)}$. The exponential explains how a small attraction produces an extremely small pairing scale, matching the Cooper instability. The finite-temperature equation can be linearized as the gap tends to zero to determine the mean-field transition. ^[ref]

For nearest-neighbor spin-singlet pairing on a square lattice, opposite signs of the pairing amplitude on the two bond directions give the displayed momentum-dependent superconducting gap function. It changes sign under a quarter-turn and has nodes on the zone diagonals. This sign structure is distinct from a nonnegative gap whose magnitude is merely anisotropic. A real pure $d_{x^2-y^2}$ pattern does not by itself require broken time reversal.

The superconducting gap function is a momentum-dependent pairing amplitude $\Delta (\mathbf{k})$, including a phase as well as a magnitude. A fully gapped isotropic state and a state with symmetry-required nodes can have different low-temperature responses. Heat capacity, thermal transport, London penetration depth and tunnelling spectra probe the low-energy quasiparticle spectrum. Activated behavior suggests a nonzero minimum gap; power laws can indicate nodes. For example, clean line nodes give a penetration-depth correction linear in temperature, whereas disorder can change the apparent power.

Such magnitude-sensitive probes require care: impurities, several bands, anisotropic full gaps and surface states can imitate or modify simple expectations. A node does not by itself establish a particular sign pattern, and the absence of a coherence peak is not a complete symmetry determination. The strongest identification combines momentum-sensitive spectra with phase-sensitive superconducting gap experiments.

For an illustrative $d_{x^2-y^2}$ state, $\Delta (\phi )\propto \cos 2\phi$ changes sign under a $90^{\circ }$ rotation. A Josephson junction to a conventional s-wave reference can turn that sign into an intrinsic phase shift. In a corner DC SQUID with junctions on orthogonal crystal faces, one branch can acquire an extra $\pi$ relative to the other. For equal junctions and negligible loop inductance,Changing ${\delta }_{\mathrm{int}}$ from zero to $\pi$ shifts the interference pattern by half a flux period. The 1993 YBCO–Pb experiment compared phase-coherent junction geometries and found evidence for that sign reversal, while explicitly discussing SQUID asymmetry and trapped vortices. Those controls matter: an arbitrary shifted trace is not by itself a proof of pairing symmetry.^[ref]

A tricrystal half-flux experiment arranges grain-boundary junctions so that a sign-changing order parameter produces an odd total $\pi$ shift around a ring. Fluxoid consistency then favors a half-integer flux state, with the detailed spontaneous flux depending on loop inductance and junction strengths. Choosing comparison geometries without that frustration and controlling trapped external flux separates the pairing-phase effect from ordinary flux trapping.^[ref]

The conclusion is strongest when the same candidate symmetry explains nodes, crystal-axis dependence and these phase-sensitive interference results. The phase-sensitive observation distinguishes a sign-changing gap from a merely anisotropic positive gap; no single temperature power law supplies that distinction.

The gap feature in a superconducting single-particle excitation spectrum. In a simple BCS model, excitations have $E_{\mathbf{k}}=\sqrt{{\xi }_{\mathbf{k}}^2+|\Delta (\mathbf{k}){|}^2}$. The superconducting gap function specifies the pairing amplitude and its phase; its magnitude need not be constant, and nodes can leave gapless excitations.

An unconventional superconductor realizes unconventional superconductivity: its pairing cannot be described by the simple conventional isotropic spin-singlet model. The precise usage should be stated, since unconventional gap symmetry and an unconventional microscopic pairing mechanism are different claims.

A d-wave superconductor supplies a concrete example. Its superconducting gap function changes sign with momentum direction and can vanish at nodes, permitting low-energy Bogoliubov quasiparticles. Nodal quasiparticle power laws probe those excitations, while a phase-sensitive test of d-wave pairing probes the relative gap signs. An unusual superconducting transition temperature alone does not establish a particular pairing symmetry, and a real d-wave gap does not automatically imply broken time reversal.