Symmetric and skew-symmetric Cayley transforms ($C=(I-B)(I+B{)}^{-1}$)

For a real skew-symmetric matrix $B$, its Cayley transform of a real skew-symmetric matrix with the opposite sign convention has inverse $C^{-1}=(I+B)(I-B{)}^{-1}$. Since $C$ is an orthogonal matrix, symmetry means $C=C^{-1}$, or $(I-B{)}^2=(I+B{)}^2$. This forces $B=0$. Skew-symmetry means $C=-C^{-1}$, or $(I-B{)}^2=-(I+B{)}^2$, which is equivalent to $B^2=-I$. In that case $C=-B$. Such examples exist in even dimension by taking two-dimensional right-angle rotation matrices in diagonal blocks; in odd real dimension the determinant equation $(\det B{)}^2=(-1{)}^n$ rules them out.