Three-dimensional improper orthogonal transformation

A real orthogonal matrix $T$ of size three with $\det T=-1$ has an eigenvector $n$ of eigenvalue $-1$. Its orthogonal complement is invariant, and the restriction there is an orientation-preserving plane rotation. Thus $T$ is a rotation about the axis $\mathbb{R}n$ composed with a reflection across the plane perpendicular to $n$. Writing the plane angle as $\varphi$, $\mathrm{tr}T=-1+2\cos \varphi$. A pure plane reflection is the case $\varphi =0$; if $\det (T-I)\ne 0$, it cannot be a pure plane reflection.