Two-carrier Hall coefficient ($R_H=\frac{p{\mu }_h^2-n{\mu }_e^2}{e(p{\mu }_h+n{\mu }_e{)}^2}$)

For isotropic electrons and electron holes with positive mobilities, adding their weak-field electrical conductivity tensors and imposing zero transverse total current givesThe Hall coefficient changes sign at $p{\mu }_h^2=n{\mu }_e^2$. Carrier abundance alone does not fix the sign; mobilities enter quadratically. The formula assumes ${\mu }_{e}B\ll 1$, ${\mu }_{h}B\ll 1$, independent semiclassical carriers, and no anomalous Hall contribution.

For fully ionized uncompensated acceptors, $p-n=N_A$ and $np=n_i^2$. If $r_{\mu }={\mu }_e/{\mu }_h>1$, the weak-field two-carrier Hall coefficient is positive when $p>r_{\mu }{n}_i$, giving the displayed sign threshold. A nearly constant Hall coefficient requires a stronger plateau condition. When $N_A\gg n_i$, its relative correction to $1/(e{N}_A)$ is approximately $-(1+r_{\mu }{)}^2(n_i/N_A{)}^2$. Thus specifying only that the coefficient is approximately constant does not define an exact minimum dopant concentration without a tolerance and mobility assumptions.