Replace the applied field in the doublet response by the Weiss molecular field . At zero applied field,The equation is odd in , so the two ordered orientations have equal magnitude. With , defineThe mean-field self-consistency equation becomesPlot and . The second has slope at zero and is concave for positive . For it starts above the straight line but is below it by , giving one positive intersection. For , for every . HenceAt the limiting solution is . The onset of spontaneous magnetization is the mean-field Curie temperature.
Weiss molecular field 2026-10-18
The Weiss molecular field replaces exchange coupling to neighbouring moments by an effective local field proportional to the average magnetization. For two-state moments and , self-consistency gives at zero applied field, where and , with . This field represents a quantum exchange energy, not generally the actual magnetostatic field generated by the moments.