The Heisenberg model couples neighboring or more general pairs of spins through . For all-to-all equal coupling, the Hamiltonian can be written in terms of the square of the total spin.
With , a computational basis vector containing excitations has eigenvalue . There are distinct eigenspaces, of dimensions . Any Hamiltonian commuting with preserves each sector and their population weights. In particular, a state supported in one sector cannot be transferred to a different sector by such controls.
For , Pauli commutators give cancellation between the and terms in , while each term commutes individually. Hence total spin magnetization is conserved. Local controls preserve the same law, so dynamics split into fixed-excitation sectors even when a particular sector is controllable.
For a network of spin-one-half sites with and , the single-excitation subspace has exactly one spin in state and dimension . Excitation-conserving exchange interactions preserve it. Its restricted Hamiltonian is a hopping matrix whose entries connect the corresponding sites. Controllability within this subspace need not imply controllability on the full -dimensional space.
The isotropic XY exchange interaction between two qubits is . Its action isIndeed, , , , and . The two terms cancel on equal bits and add on unequal bits. Thus a network Hamiltonian operator preserves excitation number; in the single-excitation subspace, it is the weighted adjacency matrix, moving an excitation from to with hopping coefficient .
Consider identical length- arms joined to one hub, with XY exchange interactions of strength from the hub to each first site and strength between sites on each arm. Let be the hub excitation and . This orthonormal symmetric single-excitation subspace is invariant, and its restricted Hamiltonian operator iswith endpoint terms omitted. At the first link the hub contributions add to ; all other links act identically on the arms. Thus the linear isometry intertwines with the path Hamiltonian operator : . Expanding the matrix exponential gives . Perfect quantum state transfer from zero to on the path therefore produces an equal excitation superposition at the arm tips. Since all other qubits are zero, the tip state is a pure W state, up to the transfer's common phase.
In the single-excitation subspace, take a connected real nearest-neighbor hopping matrix with every coupling nonzero and endpoint control . Endpoint commutators isolate the first transition, then propagate along the chain to generate both off-diagonal skew-Hermitian directions and adjacent diagonal differences. These generate . For , supplies the central direction, giving . For the algebra is , which still gives full state controllability but omits an arbitrary global phase. A broken coupling separates an unreachable chain component.
A Heisenberg antiferromagnet has positive exchange coupling in , so neighboring spins energetically prefer antiparallel alignment.
A bipartite spin rotation rotates the spin on one sublattice by , converting an alternating classical Néel state to an all-up reference state. Rotation about sends and on that sublattice. For an isotropic nearest-neighbor Heisenberg antiferromagnet, a bond becomes . The transformation is unitary and preserves the spin commutation relations; it changes the reference frame, not the model's spectrum.
A Heisenberg ferromagnet has negative exchange coupling in , so neighboring spins energetically prefer parallel alignment.
A connected isotropic spin- ferromagnet with positive exchanges has a fully polarized ground state and a maximal-total-spin multiplet. For sites the total spin is , with magnetic states generated by total-spin lowering. Global rotations span the same degenerate space. Slowly varying reorientations produce gapless ferromagnetic magnons; finite-volume degeneracy must be distinguished from a thermodynamic statement about spontaneous order.
For two spin-one-half particles,has two eigenvalues and two further eigenvaluesFor positive , the zero-field limit has a unique spin-one-half singlet state ground state and a triply degenerate spin-one-half triplet state excited level.
For spin-one-half systems and one term per unordered pair,Its minimum lies in the smallest available total-spin sector.
For a bipartite spin-one-half Heisenberg antiferromagnet with coordination , the two-sublattice mean-field state becomes exact. Antiparallel pure Bloch vectors give bond energy for the convention .
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