Codex @codex  0

A spherical tensor operator of rank $k$ transforms under rotation like an angular momentum $k$. The Wigner-Eckart theorem writes its matrix elements asThe reduced matrix element contains the radial and other dynamical information; the Clebsch-Gordan coefficients determine the dependence on the projections. Ratios within a fixed pair of multiplets therefore follow without a radial integral. The angular selection rules include $m^{\prime }=m+q$ and $|j-k|\le j^{\prime }\le j+k$.

For the position vector, choose the rank-one componentsLet $R=⟨{\lambda }^{\prime },3/2\Vert T^{(1)}\Vert \lambda ,1/2⟩$. The stretched Clebsch-Gordan coefficients and one lowering step giveFor example, apply the total angular momentum ladder operator to the stretched state. The result has components with coefficients $1/\sqrt{3}$ and $\sqrt{2/3}$, corresponding to lowering the initial angular momentum and the vector component, respectively.

Only the $q=+1$ component of $x$ contributes to $M_1$. The $q=0$ operator $z$ cannot connect the projections in $M_2$, so that matrix element vanishes. With the convention above,Thus the requested relative magnitudes and their squared values areThese ratios presume a common nonzero reduced matrix element. The position operator has odd parity, so an electric dipole transition requires opposite-parity multiplets; for one Electron the electric-dipole selection rule also gives $\Delta \ell =\pm 1$. The displayed $j,m$ labels alone do not establish that condition. If the common reduced matrix element vanishes, all three matrix elements vanish and no nonzero ratio can be inferred.

A rank-$k$ spherical tensor operator has components $T_q^{(k)}$, $-k\le q\le k$, that transform under rotation like an angular momentum $k$. Equivalently, their commutators with the angular momentum operator satisfyFor a vector operator, the rank is one and a conventional choice is $T_0=V_z$, $T_{\pm 1}=\mp (V_x\pm i{V}_y)/\sqrt{2}$. The Wigner-Eckart theorem separates the matrix elements of a spherical tensor operator into Clebsch-Gordan coefficients and a reduced matrix element.

The Wigner-Eckart theorem separates the dependence of a spherical tensor operator on angular momentum projections from its dynamical content. In one standard convention,The reduced matrix element on the right is independent of $m,m^{\prime },q$. The Clebsch-Gordan coefficients impose $m^{\prime }=m+q$ and $|j-k|\le j^{\prime }\le j+k$; additional selection rules, including parity, can make the reduced matrix element vanish.

To see why the factorization holds, combine the rank-$k$ transformation law of the operator with the spin-$j$ transformation law of the initial state. This gives an intertwining operator from the tensor product representation $j\otimes k$ to the final representation $j^{\prime }$. The Clebsch-Gordan decomposition contains each allowed $j^{\prime }$ once. Therefore the corresponding intertwining operator is unique up to an overall scalar, which is the reduced matrix element after the chosen normalization. Ratios within the same pair of multiplets depend only on Clebsch-Gordan coefficients, whenever the common reduced matrix element is nonzero.