Peter Debye Created 2026-10-18 Updated 2026-11-05
Peter Debye explained the heat capacity of a solid by counting a spectrum of quantized elastic vibrations. In the Debye model, a cutoff ensures the correct number of modes, while the low-frequency acoustic spectrum gives heat capacity proportional to at sufficiently low temperature. At high temperature, the same construction approaches the classical Dulong-Petit law. Connecting elastic vibrations with quantum occupation explains why a solid stores much less thermal energy at low temperature than a classical mode count predicts.[ref]
Figure 1.
Portrait of Peter Debye
. Schmelhaus / ETH Zürich; ETH-Bibliothek Zürich, Bildarchiv, Portr 00836. CC BY-SA 3.0, via Wikimedia Commons. Source.