Incoming links: Caesium standard
Small splits present in all levels due to interaction between the electron spin and the nuclear spin if it is present, i.e. the nucleus has an even number of nucleons.
As the name suggests, this energy split is very small, since the influence of the nucleus spin on the electron spin is relatively small compared to other fine structure.
TODO confirm: does it need quantum electrodynamics or is the Dirac equation enough?
The most important examples:
- hydrogen line useful in astronomy, and also the simplest possible case between 1s
- caesium standard, which is used to define the second in the International System of Units since 1967.
The Kibble balance is so precise and reproducible that it was responsible for the 2019 redefinition of the Kilogram.
It relies rely on not one, but three macroscopic quantum mechanical effects:How cool is that! As usual, the advantage of those effects is that they are discrete, and have very fixed values that don't depend either:One downside of using some quantum mechanical effects is that you have to cool everything down to 5K. But that's OK, we've got liquid helium!
- atomic spectra: basis for the caesium standard which produces precise time and frequency
- Josephson effect: basis for the Josephson voltage standard, which produces precise voltage
- quantum Hall effect: basis for the quantum Hall effect, which produces precise electrical resistance
- on the physical dimensions of any apparatus (otherwise fabrication precision would be an issue)
- small variations of temperature, magnetic field and so on
The operating principle is something along:Then, based on all this, you can determine how much the object weights.
- generate a precise frequency with a signal generator, ultimately calibrated by the Caesium standard
- use that precise frequency to generate a precise voltage with a Josephson voltage standard
- convert that precise voltage into a precise electric current by using the quantum Hall effect, which produces a very precise electrical resistance
- use that precise current to generate a precise force on the object your weighing, pushing it against gravity
- then you precisely measure both:
- local gravity with a gravimeter
- the displacement acceleration of the object with a laser setup
How We're Redefining the kg by Veritasium
. Source. The Kibble Balance, realizing the Kilogram from fundamental constants of nature by Richard Green
. Source. Presented in 2022 for a CENAM seminar, the Mexican metrology institute. The speaker is from the Canadian metrology institute- youtu.be/ZfNygYuuVAE?t=854: they don't actually use the Quantum Hall effect device during operation, they only use it to calibrate other non-quantum resistors
The Watt balance and redefining the kilogram by National Physical Laboratory
. Source. Nothing much, but fun to hear Kibble talking about his balance in beautiful English before he passed.