2s/2p energy split in the hydrogen emission spectrum, not predicted by the Dirac equation, but explained by quantum electrodynamics, which is one of the first great triumphs of that theory.
Note that for atoms with multiple electrons, 2s/2p shifts are expected: Why does 2s have less energy than 1s if they have the same principal quantum number?. The surprise was observing that on hydrogen which only has one electron.
Initial experiment: Lamb-Retherford experiment.
On the return from the train from the Shelter Island Conference in New York, Hans Bethe managed to do a non-relativistic calculation of the Lamb shift. He then published as The Electromagnetic Shift of Energy Levels by Hans Bethe (1947) which is still paywalled as of 2021, fuck me: journals.aps.org/pr/abstract/10.1103/PhysRev.72.339 by Physical Review.
The Electromagnetic Shift of Energy Levels Freeman Dyson (1948) published on Physical Review is apparently a relativistic analysis of the same: journals.aps.org/pr/abstract/10.1103/PhysRev.73.617 also paywalled as of 2021.
TODO how do the infinities show up, and how did people solve them?
www.mdpi.com/2624-8174/2/2/8/pdf History and Some Aspects of the Lamb Shift by G. Jordan Maclay (2019)
Never trust an experiment that is not supported by a good theory Updated 2024-12-15 +Created 1970-01-01
Not the usual bullshit you were expecting from the philosophy of Science, right?
Some notable quoters:
- Jacques Monod has the exact quote as presented here: pubmed.ncbi.nlm.nih.gov/22042272/, though presumably it was in French, TODO find the French version
- youtu.be/AYC5lE0b8os?t=41 A Computational Whole-Cell Model Predicts Genotype From Phenotype- Markus Covert by "Calit2ube" (2013), see also: Section "Whole cell simulation"
- the book Genius: Richard Feynman and Modern Physics by James Gleick (1994) mentions a few incidents of this involving Feynman, see e.g. chapter "New Particles, New Language" where he and fellow theorist Hans Bethe immediately spot problems with experimentalists' data in suspicious results