Continuous spectrum (functional analysis) Updated +Created
Unlike the simple case of a matrix, in infinite dimensional vector spaces, the spectrum may be continuous.
The quintessential example of that is the spectrum of the position operator in quantum mechanics, in which any real number is a possible eigenvalue, since the particle may be found in any position. The associated eigenvectors are the corresponding Dirac delta functions.
Linear map Updated +Created
A linear map is a function where and are two vector spaces over underlying fields such that:
A common case is , and .
One thing that makes such functions particularly simple is that they can be fully specified by specifyin how they act on all possible combinations of input basis vectors: they are therefore specified by only a finite number of elements of .
Every linear map in finite dimension can be represented by a matrix, the points of the domain being represented as vectors.
As such, when we say "linear map", we can think of a generalization of matrix multiplication that makes sense in infinite dimensional spaces like Hilbert spaces, since calling such infinite dimensional maps "matrices" is stretching it a bit, since we would need to specify infinitely many rows and columns.
The prototypical building block of infinite dimensional linear map is the derivative. In that case, the vectors being operated upon are functions, which cannot therefore be specified by a finite number of parameters, e.g.
For example, the left side of the time-independent Schrödinger equation is a linear map. And the time-independent Schrödinger equation can be seen as a eigenvalue problem.
Solving the Schrodinger equation with the time-independent Schrödinger equation Updated +Created
Before reading any further, you must understand heat equation solution with Fourier series, which uses separation of variables.
Once that example is clear, we see that the exact same separation of variables can be done to the Schrödinger equation. If we name the constant of the separation of variables for energy, we get:
  • a time-only part that does not depend on space and does not depend on the Hamiltonian at all. The solution for this part is therefore always the same exponentials for any problem, and this part is therefore "boring":
  • a space-only part that does not depend on time, bud does depend on the Hamiltonian:
    Since this is the only non-trivial part, unlike the time part which is trivial, this spacial part is just called "the time-independent Schrodinger equation".
    Note that the here is not the same as the in the time-dependent Schrodinger equation of course, as that psi is the result of the multiplication of the time and space parts. This is a bit of imprecise terminology, but hey, physics.
Because the time part of the equation is always the same and always trivial to solve, all we have to do to actually solve the Schrodinger equation is to solve the time independent one, and then we can construct the full solution trivially.
Once we've solved the time-independent part for each possible , we can construct a solution exactly as we did in heat equation solution with Fourier series: we make a weighted sum over all possible to match the initial condition, which is analogous to the Fourier series in the case of the heat equation to reach a final full solution:
  • if there are only discretely many possible values of , each possible energy . we proceed
    Equation 3.
    Solution of the Schrodinger equation in terms of the time-independent and time dependent parts
    .
    and this is a solution by selecting such that at time we match the initial condition:
    A finite spectrum shows up in many incredibly important cases:
  • if there are infinitely many values of E, we do something analogous but with an integral instead of a sum. This is called the continuous spectrum. One notable
The fact that this approximation of the initial condition is always possible from is mathematically proven by some version of the spectral theorem based on the fact that The Schrodinger equation Hamiltonian has to be Hermitian and therefore behaves nicely.
It is interesting to note that solving the time-independent Schrodinger equation can also be seen exactly as an eigenvalue equation where:
The only difference from usual matrix eigenvectors is that we are now dealing with an infinite dimensional vector space.
Furthermore: