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For simply connected , rational Hurewicz homomorphism identifies with the primitive elements of a Hopf algebra of and induces an isomorphism of graded Hopf algebras. The bracket on homotopy is the Samelson product. The underlying algebra theorem says that a connected graded cocommutative Hopf algebra over characteristic zero is the universal enveloping algebra of its primitive Lie algebra. These statements let a free tensor algebra of loop-space homology detect a free graded Lie algebra of homotopy.