Rotational temperature

For a linear rigid rotor, rotational temperature expresses the rotational energy constant in kelvins: $E_J=k_B{\theta }_{r}J(J+1)$, where $I$ is the perpendicular moment of inertia. With all integer $J\ge 0$ allowed and degeneracies $2J+1$, its rotational canonical partition function is $Z={\sum }_J(2J+1)e^{-{\theta }_{r}J(J+1)/T}$. It approaches $1+3e^{-2{\theta }_r/T}$ at low temperature and $T/{\theta }_r$ at high temperature. The latter limit gives mean rotational energy $k_{B}T$ and heat capacity $k_B$ per rotor.