One-body density matrix
ID: one-body-density-matrix
The one-body density matrixuses a creation operator and an annihilation operator to describe first-order spatial quantum coherence. Its diagonal is particle-number density and its trace is the expectation value of the particle number operator, . Dividing by instead gives a unit-trace convention, so the normalization matters when interpreting its eigenvalues.
For bosons, an eigenvalue that remains proportional to particle number in the thermodynamic limit identifies Bose-Einstein condensation. This criterion extends occupation of a single-particle mode to interacting systems.[ref]
Bose-Einstein Condensation and Liquid Helium by Oliver Penrose and Lars Onsager. Abstract and section 3, equations 3–4: extensive largest eigenvalue of the one-particle reduced density matrix
In a homogeneous system of volume , an occupied plane-wave mode contributesA constant long-distance limit therefore corresponds to a zero-momentum condensate; a moving condensate can retain a spatial phase. Finite local density or short-distance quantum coherence alone does not establish off-diagonal long-range order.
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