Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2023/paper-1/a3/a/i/solution

The gross requirement is an anisotropic polarizability tensor, so that changing molecular orientation changes the induced response. A permanent electric dipole moment is not required; a homonuclear diatomic can therefore have a rotational Raman scattering spectrum.
For the inelastic lines of a linear rigid rotor, the detailed rule is , with . The contribution is unshifted Rayleigh scattering, not a rotational Stokes Raman scattering line. Stokes Raman scattering has because the molecule gains rotational energy.

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